J/A+A/633/A120      SgrB2(M) 13CCC and C13CC spectra        (Giesen +, 2020)

First detection of the carbon chain molecules 13CCC and C13CC towards SgrB2(M). Giesen T.F., Mookerjea B., Fuchs G.W., Breier A.A., Witsch D., Simon R., Stutzki J. <Astron. Astrophys. 633, A120 (2020)> =2020A&A...633A.120G 2020A&A...633A.120G (SIMBAD/NED BibCode)
ADC_Keywords: Star Forming Region ; Interstellar medium ; Spectroscopy Keywords: ISM: molecules - submillimeter: ISM - molecular processes Abstract: Carbon molecules and their 13C-isotopologues can be used to determine the 12C/13C abundance ratios in stellar and interstellar objects. C3 is a pure carbon chain molecule found in star forming regions and in stellar shells of carbon-rich late-type stars. Latest laboratory data of 13C-isotopologues of C3 allow a selective search for the mono-substituted species 13CCC and C13CC based on accurate ro-vibrational frequencies. Our aim was to provide the first detection of the 13C-isotopologues ^13CCC and C13CC in space and to derive the 12C/ 13C ratio of interstellar gas in the massive star-forming region SgrB2(M) near the Galactic Center. We used the heterodyne receivers GREAT and upGREAT on board SOFIA to search for the ro-vibrational transitions Q(2) and Q(4) of 13CCC and C13CC at 1.9THz along the line of sight towards SgrB2(M). In addition, to determine the local excitation temperature we analyzed data from nine ro-vibrational transitions of the main isotopologue CCC in the frequency range between 1.6-1.9THz which were taken from the Herschel Science Data Archive. We report the first detection of the isotopologues 13CCC and C13CC. For both species the ro-vibrational absorption lines Q(2) and Q(4) have been identified, primarily arising from the warm gas physically associated with the strong continuum source SgrB2(M). From the available CCC ro-vibrational transitions we derived a gas excitation temperature of Tex=44.4+4.7-3.9K and a total column density of N(CCC)=3.88+0.39-0.35x1015cm^-2.. Assuming the excitation temperatures of C13CC and 13CCC to be the same as for CCC, we obtained column densities of the 13C-isotopologues of N(C13CC)=2.1+0.9-0.6_x1014cm-2 and N(13CCC)=2.4+1.2-0.8x1014cm-2. The derived 12C/13C abundance ratio in the C3 molecules is 20.5±4.2, which is in agreement with the elemental ratio of 20, typically observed in SgrB2(M). However, we find the N(13CCC)/N(C13CC) ratio to be 1.2±0.1, which is shifted from the statistically expected value of 2. We propose that the discrepant abundance ratio arises due to the the lower zero-point energy of C13CC which makes position- exchange reaction converting C13CC to C13CC energetically favorable. Description: The observed spectra as presented in Figures 1 and 3 of the paper are provided in FITS format with the intensity (in K) being the continuum subtracted main beam temperature. Objects: ---------------------------------------------------- RA (2000) DE Designation(s) ---------------------------------------------------- 17 47 20.5 -28 23 06 SgrB2(M) = NAME Sgr B2(M) ---------------------------------------------------- File Summary: -------------------------------------------------------------------------------- FileName Lrecl Records Explanations -------------------------------------------------------------------------------- ReadMe 80 . This file list.dat 158 12 List of fits spectra fits/* . 12 Individual fits spectra -------------------------------------------------------------------------------- See also: J/A+A/559/A47 : Sgr B2(N) and Sgr B2(M) IRAM 30m line survey (Belloche+, 2013) Byte-by-byte Description of file: list.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 9 F9.5 deg RAdeg Right Ascension of center (J2000) 10- 18 F9.5 deg DEdeg Declination of center (J2000) 20- 24 I5 --- Nx Number of pixels along X-axis 26- 48 A23 "datime" Obs.date Observation date 50- 61 E12.6 Hz bFREQ Lower value of frequency interval 63- 73 E11.6 Hz BFREQ Upper value of frequency interval 75- 85 E11.6 Hz dFREQ Frequency resolution 87- 89 I3 Kibyte size Size of FITS file 91-112 A22 --- FileName Name of FITS file, in subdirectory fits 114-158 A45 --- Title Title of the FITS file -------------------------------------------------------------------------------- Acknowledgements: Bhaswati Mookerjea, bhaswati(at)tifr.res.in
(End) Patricia Vannier [CDS] 22-Nov-2019
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